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2-(2,5-Dichloro­benzene­sulfonamido)-3-methyl­butanoic acid

机译:2-(2,5-二氯­苯­磺酰胺基)-3-甲基­丁酸

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摘要

The structure of the title compound, C11H13Cl2NO4S, shows one sulfonamide-O atom to lie almost in the plane of the benzene ring [C—C—S—O = −178.7 (2) °] and the other to one side [C—C—S—O = −49.4 (3)°]. Lying to the other side is the amine residue, which occupies a position almost perpendicular to the plane [C—S—N—C = 70.2 (2)°]; the carb­oxy­lic acid group is orientated to lie over the benzene ring. In the crystal, the appearance of an 11-membered {⋯OH⋯OCOH⋯OC2NH} synthon, which features the hy­droxy group forming both donor (to a carbonyl-O) and acceptor (from the amine-H) inter­actions, leads to the formation of a supra­molecular chain along the a axis. Chains are connected in the crystal structure by C—H⋯O contacts.
机译:标题化合物C11H13Cl2NO4S的结构显示,一个磺酰胺-O原子几乎位于苯环的平面中[CC-SO = -178.7(2)°],而另一侧位于[C- CO = -49.4 −(3)°]。另一端是胺残基,其几乎垂直于平面[CS = 70.2(2)°]。羰氧基铝酸基团的方向是位于苯环上。在晶体中,出现11元的{⋯OH⋯OCOH⋯OC2NH}合成子,其特征在于形成供体(对羰基-O)和受体(由胺-H)相互作用的羟基,导致沿a轴形成超分子链。链通过C–H = O触点以晶体结构连接。

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